Anodic Oxidation and Electropolimerization of Salicylic Acid

• Cristóbal Lárez Universidad de Los Andes, Facultad de Ciencias, Departamento de Química, Laboratorio de Polímeros
• Olga P. Márquez Universidad de Los Andes, Facultad de Ciencias, Departamento de Química Laboratorio de Electroquímica
• Jairo Márquez Universidad de Los Andes, Facultad de Ciencias, Departamento de Química Laboratorio de Electroquímica

Resumo

Electrochemical oxidation of salicylic acid is highly dependent on acidity of the electrolytic medium, due to the coexistence between protonated species, neutral species, carboxylate ions and phenoxy ions. Prevalence of one of these species, at a given pH, could explain the variation of the potential as acidity varies. In basic medium, oxidation of both carboxylate and phenoxy species takes place, while for weakly acidic or neutral media, the main reaction product is a thin resistive film that grows slowly onto the electrode surface. Ex situ FTIR reflectance measurements suggest the presence of aromatic ring segments linked by C ¾ O ¾ C and C ¾ C bonds. In situ FTIR spectra show that C ¾ C bonds appear slowly during the film growth. Initial resistivity of the film has been estimated using the model developed by Scharifker, and it was found to be within the range (1.6-2.4) 10¹¹ W cm^”“1