Design, Fabrication and Characterization of Thin-Film p-CdTe/n-CdS Solar Cells
Design, Fabrication and Characterization of Thin-Film p-CdTe/n-CdS Solar Cells
Abstract
Venezuela, due to its geographical location, richness in sources and natural resources, has a valuable potential for the use of renewable energies, especially solar. A large part of its territory is characterized by an average insolation above 3 Kwh/m2, considered suitable for photovoltaic generation. CdTe is a well-known II-VI semiconductor, which has established itself as a leader in the photovoltaic industry, has optimal properties for solar cells. This research focused on designing, manufacturing and characterizing p-CdTe/n-CdS solar cells. The design was carried out looking for the simplest and lowest cost model. The manufacturing was carried out in an Ortus-700 equipment, using the thermal evaporation technique. For the characterization of the cells, the techniques of X-ray diffraction, optical absorption and current-voltage characteristic analysis were applied. Evidence of a typical preferential orientation of a cubic structure of Zinc Blenda, direct energy gap values between 2.15 to 2.85 eV and similar performance among prepared solar cells. The manufacture and characterization of nine p-CdTe/n-CdS cells was achieved, through the formation of a p-n junction; with efficiencies of ~ 3 %.
https://doi.org/10.22209/rt.v44n2a07
Downloads
References
Alibaba. (2016). Price cadmium telluride en línea disponible en: https://spanish.alibaba.com/product-detail/pure-cdte-price-4n-5n-6n-in-stock-with-good-price-cadmium-telluride-62416992602.html (consulta: 7 abril 2020).
Bagher, A., Abadi, M, Mohsen, M. (2019). Types of solar panels. GreenMatch. Greenmatch.co.uk. en línea dispoble en: https://www.greenmatch.co.uk/blog/2015/09/types-of-solar-panels (consulta: 4 abril 2020).
Brus, L. (1984). Electron-electron and electron hole interactions in small semiconductor crystallites: The size dependence of the lowest excited electronic state. J. Chem. Phys., 80(9), 4403.
Bube, R. (2001). Encyclopedia of materials. Amsterdam: Elsevier.
Checa F., E., O. Tamp, Rosero E, E. (2015). Study of the relationship between irradiance and power genarated by PV panel based on different silicon technologies in the city of Pasto. Power Quality Aplications IEEE Workshop, 1-6.
Das, R., Pandey, S. (2011). Comparison of optical properties of b and nano crystalline thin films of CdS using different precursors. International Journal of Materials Science and Applications, 1(1), 35-40.
Demir, R., Gode, F. (2015). Structural, optical and electrical properties of nanocrystalline CdS thin films grown by chemical bath deposition method. Chalcogenide Letters, 12(2), 43-50.
Datta, S., Saha- Dasgupta, T., Saima, S. (2011). Relatibe Stability of zincblende and wurtzite structure in Cdx(x=S, Se, Te) Serie –A NMTO study arXIV 1106.
Dittrich, T. (2018). Materials concepts for solar sells. WorldScientific, Helmholtz Center Berlin for Materials and Energy, 2, 27-32.
Goh, E., Chen, T., Sun, C., Liu, Y. (2010). Thickness effect on the band gap and optical properties of germanium thin films. Journal of Applied Physics, 107(2), 024305.
Green, M., Hishikawa, Y., Dunlop, E., Levi, D., Hohl-Ebinger, J., Ho-Baillie, A. (2017). Solar cell efficiency tables (version 51). Progress in Photovoltaics: Research and Applications, 26(1), 3-12.
Hixum, M. Z., M Yu, K., Walukiewicz, W., Yu, P. S., Mao, S. (2009). Stain relaxation of CdTe films growing on lattice-mismatched sustrate. Applied Physic A, 96, 379-384.
Izovac. (2014). Vacuum tecnological equipament. RTUS-700 intructional manual, IM-0000033000. 1st edition.
Khatri, R., Vyas, S., Shah, D., Patel, P., Jani, M., Pandya, G. (2010). Study of thickness dependence optical bandgap of InSbBi thin films. International Journal of Physics and Applications, 2(3), 95-99.
Oliva, A., Solís-Canto, O., Castro-Rodríguez, R., Quintana, P. (2001). Formation Of The Band Gap Of Cds Thin films growth by different techniques. Modern Physics Letters B, 15, 671-674.
Phillips, S., Warmuth, W. (2016). Photovoltaics report. ebook. Fraunhofer Institute for Solar Energy Systems, ISE with support of PSE Projects GmbH en línea disponible en: https://www.ise.fraunhofer.de/content/dam/ise/de/documents/publications/studies/Photovoltaics-Report.pdf [consulta: 19 abril 2020].
Posso, F., González, J., Guerra, F., Gómez, H. (2014). Estimación del potencial de energía solar en Venezuela utilizando sistemas de información geográfica. Revista Geográfica Venezolana, 55(1), 27-43.
Rangel, J., Sobral, H. (2017). Optical absorption enhancement in CdTe thin films by microstructuration of the silicon substrate. Materials (Basel), 607.
Solargis. (2019). Mapas de recursos solares de Venezuela en línea disponible en: https://solargis.com/es/maps-and-gis-data/download/venezuela (consulta: 22 abril 2020).
Strauss, A. (1977). The physical properties of cadmium telluride. 12th ed. Revue Physique Appliquée, 167-184.
Copyright (c) 2021 Pedro Grima-Gallardo, Bernardo Conquet, Elías Rafael Sánchez Verde, Miguel A. Contreras-Rangel, Luis Nieves, Ana del Valle Velasquez-Velasquez, William Jose González-Escalona

This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
Copyright
La Revista Técnica de la Facultad de Ingeniería declara que los derechos de autor de los trabajos originales publicados, corresponden y son propiedad intelectual de sus autores. Los autores preservan sus derechos de autoría y publicación sin restricciones, según la licencia pública internacional no comercial ShareAlike 4.0