Synthetic aspects of the electrochemical oxidation of 4-methyl anisole

  • Oiga Márquez Universidad del Zulia-Venezuela
  • Jairo Márquez Universidad del Zulia-Venezuela
  • Reynaldo Ortiz Universidad del Zulia-Venezuela
  • Yris Martínez Universidad del Zulia-Venezuela
Palabras clave: 4-methyl anisole, anodic oxidation, electrooxidation, p-methoxy toluene

Resumen

4-methyl anisole is oxidized, in a first stage to produce a cation radical that undergoes deprotonation. Although a single oxidation peak is reported in literature corresponding to the loss of two electrons, we have been able to split it into a couple of peaks for one electron each. The cation radical is deprotonated to form a neutral radical which oxidizes to a cationic species. Two kind of reactions can occur, depending upon the reaction conditions: Whether a nucleophylic attack ofthe acetonitrile on the intermediate species, or polymerization of 4-methyl anisole.

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Cómo citar
Márquez, O., Márquez, J., Ortiz, R. y Martínez, Y. (1) «Synthetic aspects of the electrochemical oxidation of 4-methyl anisole», Revista Técnica de la Facultad de Ingeniería. Universidad del Zulia, 28(1). Disponible en: https://produccioncientificaluz.org/index.php/tecnica/article/view/5866 (Accedido: 7noviembre2024).
Sección
Artículos de Investigación