Synthesis and Characterization of bimodal mesoporous materials Ti-UVM-7 by direct incorporation into the starting gel.
Síntesis y caracterización de materiales mesoporosos bimodales Ti-UVM-7 por incorporación directa en el gel de partida
Keywords:
atrane, mesoporous, bimodal, titanium
Abstract
In this work, it was studied the synthesis of bimodal mesoporous solids Ti-UVM-7, using the synthesis strategy known as the atrane way, with incorporation of Ti into synthesis gel in Si/Ti molar ratios of 10, 25, 50 and 100. The characterizations used were: X-ray diffraction, N2 adsorption-desorption isotherms, transmission electron microscopy and X-ray energy dispersive. For all solids, X-ray patterns showed peaks around 2.02 degrees of 2θ, isotherms were type IV, with two volume steps at relative pressures of 0.4 and 0.9, typical of UVM-7 materials, and BET surface areas of 1216 to 128 m2/g, decreasing as the content of Ti increased (decrease of the Si / Ti molar ratio). The amount of Ti incorporated was too similar to that initial placed in the synthesis gel, except for the solid with a Si/Ti molar ratio of 100 (initial), which only reached Si / Ti = 127.
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References
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SOLER-ILLIA G. J. DE A. A., SANCHEZ C., LEBEAU B., PATARIN J. Chem Rev 102(11): 4093-4138. 2002.
LI Y., ZHANG L., ZHANG Q., FANG F., SUN D., LI K., WANG H., OUYANG L., ZHU M. J Phys Chem C 118(41): 23635-23644. 2014.
EL HASKOURI, J., DE ZÁRATE, D. O., GUILLEM, C., LATORRE, J., CALDÉS, M., BELTRÁN, A., BELTRÁN, D., DESCALZO, A. B., RODRÍGUEZ- LÓPEZ, G., MARTÍNEZ-MÁÑEZ, R., MARCOS, M. D., AMORÓS, P. Chem Commun, 4, 330– 331. 2002
CAMPOS R., HUERTA L., CHIRINOS J., AMORÓS P. Ciencia 18(1): 52-57. 2010.
HUERTA, L., GUILLEM, C., LATORRE, J., BELTRÁN, A., MARTÍNEZ-MÁÑEZ, R., MARCOS, M. D., BELTRÁN, D., & AMORÓS, P. Solid State Sci, 8(8): 940–951. 2006
BARRETT, E. P., JOYNER, L. G., HALENDA, P. P. J Am Chem Soc, 73(1): 373–380. 1951
BRUNAUER, S., EMMETT, P. H., TELLER, E. J Am Chem Soc, 60(2): 309–319. 1938
SING, K. S. W. Pure Appl Chem, 57(4): 603–619. 1985
EL HASKOURI J., ORTIZ DE ZÁRATE D., PÉREZ- PLA F., CERVILLA A., GUILLEM C., LATORRE J., MARCOS M. D., BELTRÁN A., BELTRÁN D., AMORÓS P. New J. Chem. 26(9): 1093–1095. 2002.
Published
2021-05-24
How to Cite
Campos, R., Primera, J., Amorós, P., & Huerta, L. (2021). Synthesis and Characterization of bimodal mesoporous materials Ti-UVM-7 by direct incorporation into the starting gel.: Síntesis y caracterización de materiales mesoporosos bimodales Ti-UVM-7 por incorporación directa en el gel de partida. Ciencia, 25(3-4), 136-142. Retrieved from https://produccioncientificaluz.org/index.php/ciencia/article/view/35987
Section
Química/Chemistry
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